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The Active-Site [4Fe-4S] Cluster in the Isoprenoid Biosynthesis Enzyme IspH Adopts Unexpected Redox States during Ligand Binding and Catalysis

https://doi.org/10.1021/jacs.3c11674

Ghebreamlak, Selamawit; Stoian, Sebastian A; Lees, Nicholas S; Cronin, Bryan; Smith, Forrest; Ross, Matthew O; Telser, Joshua; Hoffman, Brian M; Duin, Evert C (February 2024, Journal of the American Chemical Society)

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Towards a unified understanding of the copper sites in particulate methane monooxygenase: an X-ray absorption spectroscopic investigation

https://doi.org/10.1039/D1SC00676B

Cutsail, George E; Ross, Matthew O; Rosenzweig, Amy C; DeBeer, Serena (May 2021, Chemical Science)

Extended X-ray absorption fine structure spectroscopic analysis of particulate methane monooxygenase reveals only monocopper sites and investigates the possible origins of the previous observed dicopper signals.
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Coordination of the Copper Centers in Particulate Methane Monooxygenase: Comparison between Methanotrophs and Characterization of the Cu _C Site by EPR and ENDOR Spectroscopies

https://doi.org/10.1021/jacs.1c07018

Jodts, Richard J.; Ross, Matthew O.; Koo, Christopher W.; Doan, Peter E.; Rosenzweig, Amy C.; Hoffman, Brian M. (September 2021, Journal of the American Chemical Society)

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